Boise State University, “Micronano.” Aerosol Jet–Printed Piezoelectric Surface Acoustic Wave Thermometer

Product Introduction

Equipment Parameters

I. Core Research Summary

This study is compatible with Clariant’s commercial silver‑nanoparticle ink. By systematically optimizing the entire set of process parameters—including aerosol atomization, gas flow, and printing speed—we have integrated the fabrication of SAW interdigital transducers on Y‑cut LiNbO₃ piezoelectric wafers. Comprehensive characterization was performed across multiple dimensions, encompassing ink rheology, thin‑film microelectrics, RF resonance, and high‑ and low‑temperature sensing. The key findings are as follows:
  • Precise aerosol fabrication of 37 μm high-precision SAW interdigital transducers

By simulating the Reynolds number, the optimal printing working distance was determined to be 4 mm, and the sheath‑gas/carrier‑gas ratio was optimized. The resulting electrode exhibits an average line width of 32–37 μm, a metallization ratio of 0.465, and a thickness of approximately 5.3 μm, with smooth edges free of overspray or wire‑break defects. At a low sintering temperature of 200 °C, the silver film undergoes grain growth, leading to a 22.2% improvement in film densification and a 34% reduction in resistivity compared to bulk silver.

  • Dual-mode high-precision temperature sensing characteristics

The device has a reference resonant frequency of 20.75 MHz, with a sensitivity of −96.9 × 10⁻⁶/°C in the pulse‑echo (S11) mode and −92.0 × 10⁻⁶/°C in the pulse‑receive (S21) mode. Over the full temperature range, the linear fit achieves an R² as high as 0.999, and the temperature measurement resolution is as low as 1.66 × 10⁻⁷ °C, with stable performance and no resonant drift between 25 and 200 °C.

  • 6-hour long-term printing process is stable and controllable.

In the initial stage, the equipment exhibits a small amount of overspray; after 2.5 hours of continuous operation, the uniformity of the mist beam improves significantly, and over the full 6-hour run, the line width shows minimal variation. Ultrasonic treatment of the ink continuously breaks up agglomerated particles, leading to a gradual reduction in particle size during printing, thereby validating long-term production‑level consistency.

  • Maskless Digital Rapid Iterative Design

CAD allows direct modification of interdigital spacing and electrode count without the need to re‑fabricate the photolithography mask, enabling SAW device fabrication in a single batch within just a few hours and facilitating rapid optimization of resonant frequency and temperature‑sensing sensitivity parameters.

  • Damage-free, gentle processing of piezoelectric substrates

The entire process employs low-temperature forming at 70°C on the substrate, followed by only a brief post‑processing sintering at 200°C, thereby preserving the piezoelectric effect of the lithium niobate crystal and preventing substrate cracking or polarization degradation.

II. Complete SAW Fabrication Process and Core Advantages for Aerosol Jet Printing

(1) Complete SAW Thermometer Fabrication Process

  • Y‑cut LiNbO₃ piezoelectric wafer cleaning, without the need for substrate surface modification;
  • Commercial silver ink is diluted and formulated with deionized water, then ultrasonically dispersed to obtain a low-viscosity atomization ink suitable for use.
  • Optomec AJ ultrasonic atomization module, with a carrier gas flow of 35 sccm and a sheath gas flow of 55 sccm, and a constant nozzle-to-substrate distance of 4 mm.
  • At low speed, 0.25–0.4 mm/s, print the interdigitated active region; at high speed, 0.8 mm/s, deposit the solder pads.
  • Sintering in a 200°C oven for 1 hour promotes silver particle grain growth and yields a dense, conductive film.
  • The probe station, paired with a vector network analyzer, is used to acquire S11 and S21 RF curves for characterizing the temperature-sensing performance.

(II) Five Core Processes (Comparison of Lithography and Inkjet)

  • The subtractive process is perfectly replaced, with a green, non-corrosive waste liquid.

By eliminating the conventional microfabrication workflow involving sputtering, photolithography, and chemical etching, and avoiding the use of strong acids and bases, environmental‑friendly processing costs are significantly reduced, enabling small and medium‑sized laboratories to develop SAW devices without requiring a cleanroom production line.

  • Micron-level high-precision molding, with edge morphology far superior to inkjet.

Aerosol-focused microbeams suppress spattering, while the electrode edges are smooth and exhibit uniform line width; in contrast, inkjet-printed lines suffer from spreading and burrs, severely degrading the SAW resonator’s quality factor.

  • Wide safety spray distance compatible with irregular-shaped piezoelectric substrates.

A stable working distance of 4 mm ensures that even slight surface undulations on the wafer do not compromise print quality, with the capability to extend to conformal printing of curved‑surface piezoelectric components in the future.

  • Redesign and zero‑tooling costs, with R&D cycles significantly shortened.

Changing the interdigitated electrode layout requires only revising the design files; lithography for each mask set takes 7–15 days, and aerosol‑based prototyping of the new structure is completed on the same day.

  • Low-temperature flexibility and compatibility, universally applicable to all types of piezoelectric materials.

During the printing process, the substrate temperature is only 70°C, making it compatible with the entire range of piezoelectric substrates—including lithium niobate, lithium tantalate, and aluminum nitride—without compromising the crystal’s polarization properties.

III. Five Core Technological Innovations of This Study

Innovation 1: A SAW-based aerosol standardization process window optimized through Reynolds-number simulations.

By means of fluid dynamics calculations, we determine the optimal working distance and airflow ratio, quantitatively elucidate the causes of overspray, and establish a reusable parameter framework for piezoelectric MEMS aerosol printing.

Innovative Scheme for Long-Term Stable Atomization of Ink

By employing in-situ ultrasonic dispersion of silver particles directly on the equipment, this solution addresses industry‑wide challenges such as ink agglomeration and inconsistent line width during batch printing, enabling 6-hour continuous, stable production.

Innovative SAW device with three dual‑RF‑channel cooperative temperature‑sensing capabilities

Simultaneously extract the resonance frequency shifts of S11 and S21, balancing high precision and low noise under two distinct detection conditions, and compatible with the readout circuits of various industrial temperature‑measurement devices.

Innovative Low-Temperature Sintering Scheme for Densifying Aerosol-Printed Silver Films

Short‑time heat treatment at 200°C significantly enhances the film’s densification, enabling highly conductive interdigital electrodes without compromising the piezoelectric crystal and thereby ensuring strong SAW resonance signal strength.

Innovative New Paradigm for Low-Cost, Passive MEMS Sensor Additive Manufacturing

Breaking the conventional wisdom that SAW devices require advanced microfabrication, a benchtop aerosol‑based system can now fabricate an entire resonant‑sensor chip.

IV. Existing Process Challenges and Corresponding Solutions for Overcoming Them

Challenge 1: Traditional lithography processes are complex, highly polluting, and involve long prototyping cycles.

✅ Breaks new ground in aerosol jet additive manufacturing, requiring no masks or etching processes, and enabling sample fabrication in just a few hours, significantly reducing R&D and environmental costs.

Challenge 2: The edges of inkjet-printed electrodes are rough, resulting in significant SAW resonator loss and poor linearity.

✅ Breakthrough in sheath‑gas‑focused microbeam precision shaping, with clean electrode edges and a significant enhancement in device quality factor; temperature‑measurement linearity (R²) approaches 1.

Challenge 3: Aerosol-based inks tend to agglomerate during prolonged printing, causing the printed lines to gradually thicken.

✅ Breakthrough in the continuous ultrasonic atomization system: particle size is continuously refined during printing, and line‑width variation over 6 hours of mass production is kept within an extremely narrow range.

Challenge 4: The nozzle-to-substrate gap is highly sensitive, and uneven wafers are prone to wire breakage.

✅ Breaks the 4 mm tolerance for working distance, and slight variations in substrate height do not compromise electrode continuity.

Challenge 5: High-temperature treatment can degrade the polarization properties of piezoelectric crystals.

✅ The entire printing process operates at a low temperature of 70°C, with only a brief 200°C sintering step in the final stage, ensuring no degradation of the piezoelectric substrate’s performance.

V. Future Diversified Industrial Application Scenarios

1 High-Temperature Industrial Passive Temperature-Sensing Node

Metallurgical and heat‑treatment furnaces, as well as in‑pipe passive SAW sensors, require no wiring for power supply and provide long‑term, stable temperature monitoring up to 200°C.

2 Onboard Wireless Temperature Measurement for Aircraft Engines

Turbine blades and miniature passive SAW chips for high-temperature cavities—battery-free, capable of withstanding extreme operating temperatures, and enabling real-time acquisition of thermal distribution.

3. Internal Condition Monitoring of Nuclear Power Equipment

The reactor features a compact, sealed cavity and employs passive, wireless temperature sensing, thereby eliminating the challenges associated with cable high-temperature resistance and radiation‑induced aging.

4 Acoustic Devices for Microfluidic Chips

Microfluidic laboratory: SAW droplet‑manipulation chip with a rapidly iterated interdigitated electrode structure, shortening the development cycle of biochemical chips.

5. University-level MEMS Teaching and Research Platform

Without the need for an expensive lithography microfabrication line, a desktop aerosol‑based platform enables rapid fabrication of various SAW resonator and sensor prototype devices.
Image and Text Guide

Figure 1 shows a schematic of aerosol jet printing for SAW devices. In this process, ultrasonically atomized nanoparticle ink droplets are delivered from the ink reservoir to the print head, where they are focused into an ordered stream and deposited onto the surface of a piezoelectric substrate. The operating principle of a SAW device is to convert an applied voltage into an acoustic wave, which propagates along the substrate surface at a material‑specific speed, VSAW; upon reaching the receiver, the acoustic wave is converted back into a readable electrical signal.

Figure 2. Rheological properties of silver nanoparticle ink for AJP: a) Dynamic light scattering spectrum of silver nanoparticles suspended in water (used for hydrodynamic particle size determination); b) Drop‑test images (used to measure the ink’s surface tension); c) Contact angle receding curve of the silver nanoparticle ink on a lithium niobate surface, with the inset showing the Young’s contact angle measured 10 seconds after deposition.

Table 1: Summary of AJP Parameters

Figure 3 shows the instrument drift and print‑quality assessment during a 6‑hour AJP experiment: (a) the time‑dependent curves of carrier‑gas and sheath‑gas feedback pressures; (b) a 50× micrograph of a printed line, with a measured line width of approximately 35 μm; and (c–e), 5× micrographs illustrating, at (c) 1 hour, (d) 3 hours, and (e) 5 hours, the improved print‑line quality and reduced spattering.

Figure 4. Structure and electrical properties of printed silver devices. a X-ray diffraction patterns of silver nanoparticle ink deposited on a glass substrate, showing the spectrum before and after sintering at 200°C; crystallographic planes of the silver thin film are labeled above the corresponding diffraction peaks. b Stitched micrographs with dimension annotations of a printed four‑point device used for electrical characterization. c Tip‑profile measurement of the printed four‑point structure. d Average line profiles of the effective conductive paths in the four‑point device. e Resistance–temperature dependence of the printed silver four‑point structure.

Figure 5. Schematic diagram of the design and structure of a printed surface acoustic wave (SAW) device. a shows a stitched micrograph of the printed SAW device, with dimensions labeled; the inset clearly illustrates the effective electrode width and pitch. b and c are tip‑profile measurements of the printed SAW device. d presents the average height and width data of the finger‑like electrode structures obtained via three‑dimensional scanning.

Figure 6. Characteristics and temperature response of AJ‑printed surface acoustic wave devices: (a) S11 and (d) S21 measured before and after time‑gating at room temperature; (b) S11 and (e) S21 measured at room temperature and 200 °C after time‑gating; and the thermal drift of the fundamental frequency f(T), obtained from (c) S11 and (f) S21 after gating, as the ambient temperature is ramped up from 25 °C in 5 °C increments to 200 °C in 5 °C increments.

Table 2 Performance of the AJ-Printed SAW Thermometer

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