“ACS Appl. Electron. Mater.”: Aerosol Jet Printing and Photonic Rapid Sintering of a Flexible Multimodal Sensor for Simultaneous Temperature and Strain Sensing

Product Introduction

Equipment Parameters

I. Core Research Summary

This study employs the Optomec AJ300 aerosol‑jet platform to formulate dual‑functional inks based on gold nanoparticles and ITO nanoparticles, respectively. Strain‑resistance sensors and thermocouple junctions are sequentially printed onto a polyimide (PI) flexible substrate, followed by pulsed xenon‑flash sintering at ultrahigh speed. Comprehensive validation of morphology, electrical performance, and high–low temperature mechanical reliability is then carried out. The key findings are as follows:
  • Dual-mode integrated sensing structure

The same device integrates a serpentine gold strain gauge and a gold/ITO thin-film thermocouple, enabling AC‑signal measurement of strain resistance and DC Seebeck‑voltage measurement of temperature. This allows for in‑situ, real‑time compensation of temperature‑induced strain drift, eliminating the need for complex external decoupling algorithms. The thermocouple exhibits a thermoelectric sensitivity of 51.6 μV/°C, while the strain gauge has a gauge factor of 2.5; the overall performance surpasses that of commercial patch‑type sensors.

  • Millisecond-scale photon-flashing low-temperature sintering process

The entire sintering process takes less than 2 seconds; xenon‑lamp irradiation selectively heats and raises the temperature of the nano‑conductive layer, while the PI flexible substrate remains at a low temperature throughout, eliminating the warping and aging of the substrate that result from conventional high‑temperature baking lasting several hours. Meanwhile, gold and ITO film particles achieve thorough fusion, significantly enhancing electrical conductivity and continuity.

  • Ultra-wide, high-temperature-stable service range

The sensor can stably operate at 350°C over long periods; after 15 days of continuous high‑temperature immersion and seven thermal cycling cycles, its thermoelectric output and strain‑gauge resistance exhibit virtually no drift. Following 500 bending/torsion cycles, the sensing performance degrades by less than 5%, and after 10,000 bending cycles, the performance reduction is only 7%, demonstrating outstanding mechanical durability.

  • Multi-substrate universal compatible printing system

The aerosol‑based process is compatible with four types of substrates—polyimide, polyurethane, mica, and glass—and can be used to flexibly fabricate both flexible and rigid sensing units tailored to the curvature and material properties of various devices, making it suitable for a wide range of industrial monitoring components.

  • Digital Maskless Rapid Development

With CAD, the strain gauge’s length and width, as well as the thermocouple dimensions, can be modified with a single click; gold and ITO inks can be rapidly switched via atomization, eliminating the need for photolithographic masks. This enables the rapid fabrication and iterative optimization of novel high-temperature sensing samples within just a few hours.

II. Complete Preparation Process and Core Advantages of Aerosol Spraying

(1) Complete Dual-Mode Sensor Production Process

  • PI flexible substrate undergoes plasma cleaning to remove oil and contaminants, ensuring film adhesion.
  • Ultrasonic atomization of gold nanoparticle ink, aerosol‑based CNC printing of a serpentine strain gauge and a thermoelectric electrode on one side;
  • Switch to ITO nanoink, print the electrode on the opposite side in a crosswise pattern, and form a temperature-sensing junction at the Au/ITO interface.
  • Xenon‑gas pulsed flash sintering system, 2 kV voltage, 800 µs pulse duration, three‑shot flash sintering, with total sintering time under 2 seconds.
  • After cooling, four‑wire electrical calibration was performed, and simultaneous thermal‑strain testing was completed using a high‑temperature muffle furnace and a cantilever beam platform.

(II) Five Core Process Advantages (Comparison with Lithography, Screen Printing, and Conventional Thermal Sintering)

  • In-situ integrated molding of multiple materials eliminates the need for multiple patching steps.

The same device enables continuous printing of both strain‑sensing and temperature‑sensing circuitry in a single layer, featuring an integrated dual‑mode sensing unit with adhesive‑free delamination and an air‑gap thermal insulation layer, resulting in a substantial improvement in measurement accuracy.

  • Ultrafast photonic sintering, with zero thermal damage to flexible substrates.

Unlike conventional ovens that subject materials to high‑temperature heating for hundreds of minutes, flash heating relies solely on the heat absorption of metallic nanoparticles, leaving the polymeric substrate unaffected by thermal shock and ensuring that the ultra‑thin, flexible film retains its shape.

  • Micron-level high-precision conformal printing, compatible with irregularly shaped curved components.

Aerosol printing with a 3–5 mm tolerance in print pitch enables direct deposition of sensing circuits on turbine blades and curved pipe outer surfaces, where conventional patch‑on methods struggle to conform to complex geometries.

  • Broad substrate compatibility; both soft and rigid components can be fabricated.

PI, PU, mica, and glass all share a single set of printing parameters, balancing the needs of flexible wearable devices with those of rigid high‑temperature industrial component monitoring.

  • Maskless digital R&D significantly reduces trial-and-error costs.

No custom lithography masks are required; by adjusting the strain‑grid layout, new samples can be produced on the same day, shortening the iterative cycle for high‑temperature sensing formulations by 80%.

III. Five Key Technological Innovations

Innovation 1: A novel fabrication system combining aerosol-based multi-material direct writing with photonic flash processing.

Innovation has enabled the integration of aerosol-based multi-material additive manufacturing with millisecond pulsed flash sintering, facilitating the rapid, monolithic fabrication of a dual-mode high-temperature sensor comprising gold and ITO.

Innovation 2: An in-situ thermoelectric self-compensation architecture that eliminates high-temperature strain‑induced temperature drift.

Gold–ITO thermocouple junctions enable synchronous acquisition of the true temperature at measurement points, with hardware‑level correction of resistance‑temperature drift, thereby simplifying the backend signal‑processing algorithms.

Innovative selective photothermal sintering mechanism, balancing high electrical conductivity with flexible substrate protection.

By leveraging the surface plasmon resonance effect of metals to achieve directional absorption of flash‑lamp energy, only the sensing layer is densified while the PI substrate remains at room temperature, thereby addressing a major industry challenge: material degradation during high‑temperature sintering.

Innovative 4 350℃ long-term stable high-temperature-resistant sensing system

Gold–ITO nanocomposite thin films exhibit excellent oxidation resistance, with virtually no degradation in high‑temperature immersion or thermal cycling performance over long periods, making them well suited for extreme operating conditions in aerospace and energy applications.

Innovation: Standardized Process for Universal Curved-Surface Conformal Sensing

A set of aerosol‑printing parameters is compatible with both flexible thin films and rigid metal substrates, enabling the large‑scale fabrication of monitoring sensor arrays with various non‑planar architectures.

IV. Existing Process Challenges and Corresponding Solutions for Overcoming Them

Challenge 1: There is a gap between the split-type strain gauge and the thermocouple during bonding, leading to significant temperature-compensation errors.

✅ Breakthrough in integrated aerosol co-deposition: dual-sensor units are simultaneously fabricated on the same plane, with measurement points perfectly aligned, resulting in a significant improvement in temperature‑drift compensation accuracy.

Challenge 2: Conventional oven-based thermal sintering is time-consuming and, at high temperatures, can degrade flexible substrates such as PI.

✅ Breaks through the 2-second pulsed flash sintering limitation, selectively sintering only conductive nanoparticles while keeping the substrate at low temperature with no visible deformation or aging.

Challenge 3: Conventional printed films are prone to oxidation at high temperatures, leading to a decline in long-term service performance.

✅ Gold/ITO dual‑metallic system combined with flash densification yields a thin film with low porosity and stable performance under prolonged operation at 350°C.

Challenge 4: Lithography and screen printing can only perform planar processing, making it impossible to deploy sensors on curved surfaces such as turbines and pipelines.

✅ Aerosol-based, non-contact mist beam enables direct printing of continuous sensing circuits onto the surfaces of arbitrarily curved components.

Challenge 5: Multimodal sensor fabrication is complex, and the development cycle for new products can extend to several weeks.

✅ Maskless digital direct writing enables rapid prototyping of sensor array designs, significantly reducing R&D costs.

V. Future Diversified Industrial Application Scenarios

1. High-Temperature Monitoring of Aeroengine Turbine Blades

A curved‑surface, in‑situ aerosol‑printed thermo‑strain dual‑mode sensor that captures thermal stress and surface temperature in real time, enabling early prediction of fatigue cracks.

2. Structural Monitoring of High-Temperature Piping in Thermal and Nuclear Power Plants

A flexible sensing array for the outer walls of boilers and heat-exchanger pipelines enables long-term, high-temperature simultaneous monitoring of wall deformation and thermal distribution, providing early warning of leakage risks.

3 Soft-Robotics–Inspired Flexible Sensing

Robotic arms and inflatable actuators incorporate PI‑based sensing films that enable simultaneous detection of deformation and operating temperature during motion.

4. Monitoring of Power Battery Packs for New Energy Vehicles

Curved, ultra-thin battery‑pack housing with integrated sensing capabilities that continuously monitors thermal expansion and temperature, providing early warnings of potential thermal runaway risks.

5. High-Performance Sensing Rapid Prototyping Platform for Universities

Desktop aerosol‑plus‑flash sintering simple production line, enabling low‑cost, rapid development of various high‑temperature dual‑mode sensor prototypes.
Image and Text Guide

Figure 1. Schematic illustration showing: (a) the AJP‑based structure of a multimodal sensor on a polyimide substrate; (b) the IPL sintering process and sintering conditions for the printed film; (c) optical images of the sensor printed on a flexible polyimide substrate, along with high‑magnification views of localized regions of the printed thermocouples and strain sensors; (d) applications of aerosol‑jet‑printed sensors subjected to IPL sintering on other substrates: (i) a multimodal sensor on a glass substrate; (ii) a printed thermistor on a PUD substrate; (iii) a strain gauge on a mica substrate.

Figure 2. Scanning electron microscope images of gold and ITO materials fabricated by aerosol jet printing illustrate the surface morphologies of the following samples: (a) unsintered gold; (b) IPL‑sintered gold; (c) gold sintered at 800°C; (d) unsintered ITO; (e) IPL‑sintered ITO; (f) ITO sintered at 800°C. The figure also shows the electrical conductivity values of IPL‑sintered gold (g) and ITO (h) at different pulse durations, with error bars representing the standard deviation across five samples.

Figure 3. (a) Thermoelectric response of printed Au/ITO thermocouples during heating and cooling; (b) Stability of temperature measurements; (c) Comparison of the thermoelectric voltage output of IPL-sintered sensors versus thermally sintered sensors as a function of temperature difference. Sensors 1–3 are all IPL-sintered.

Figure 4. Synchronous measurements of temperature and strain under room-temperature (RT) and elevated-temperature conditions. Relative resistance changes of the strain gauge at different strains: (a) at room temperature; (b) a comparison of test results between the thermosensitive sensor and the IPL-sintered sensor at room temperature, along with the performance of this sensor at (c) 200°C and (d) 350°C.

Table 1. Comparison of Various Parameters of Strain Gauges in the Literature

Figure 5. Performance of the multimodal sensor before and after 15 days of thermal aging at 350°C. Thermoelectric voltage output as a function of temperature difference: (a) variation before and after thermal aging; (b) variation after multiple heating–cooling cycles. Strain‑gauge resistance: (c) variation before and after thermal aging; (d) variation during repeated thermal cycling.

Figure 6. (a) Performance of the printed temperature sensor before and after 500 bending–twisting cycles, and (b) performance of the strain gauge before and after 500 bending cycles.

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